a comparison of the hydrothermal alteration systems around the mo-hosting white pine intrusion, utah, and the buckingham porphyry, nevada
abstract
the white pine fork mo porphyry has an estimated resource of 16 mt of mo at 0.1%
mo. the host intrusions are k-feldspar- and quartz-porphyritic monzo- to syeno-granites
characterised by lree enrichment, fractionated hrees and negative nb, ta, sr and ti
anomalies, consistent with a subarc mantle melt source. the granites also have an adakitic
geochemical signature. a u-pb age for zircon from a clast in the mineralized breccia pipe at
white pine yielded an age of 26.52±0.42 ma, which falls within the error of the white pine
intrusion age of 26.61±0.24 ma. re-os ages for duplicate samples of the mo-mineralised quartz
breccia are 30.21±0.14 and 29.84±0.15 ma, which correlate with the age of the little
cottonwood stock rather than the host intrusion and may represent re-os inheritance. in
contrast, buckingham mo (-cu) porphyry has an estimated resource of 1,000 mt of mo at 0.1%
mo and is hosted in cretaceous k-feldspar- and quartz-porphyritic granites. four feldspar- and
quartz-porphyritic granites in the area were dated using la-icp-ms u-pb of zircon and yielded
ages of 38.68±0.53, 39.28±0.58, 40.76±0.41, and 40.81±0.51 ma and therefore unrelated to the
buckingham deposit, and instead are correlated with tertiary magmatism associated with au
skarns in the nearby battle mountain district. the tertiary intrusions are feldspar- and quartz
porphyritic granites. primitive mantle-normalized geochemistry of both suites of intrusive rocks
have lree enrichment, fractionated hree, negative nb, ta and ti anomalies and a slight
enrichment of zr and hf, consistent with a subarc mantle source for both suites.
the most prominent alteration in both systems is phyllic alteration comprising an
assemblage of white micas, quartz and pyrite. potassic alteration was also observed at the white
pine fork mo breccia pipe and kaolinite and chlorite observed in swir data suggest advanced
argillic alteration around the buckingham system. these petrographic observations are substantiated by the whole rock geochemistry. the potassic, phyllic, and possible advanced
argillic alteration were mapped out by the absolute values of trace elements. the trace element
geochemistry of quartz and pyrite can be used to fingerprint deposit types and as vectors towards
mineralisation in alteration systems around ore deposits. at white pine fork, the hydrothermal
quartz is characterised by higher ti and as than the igneous quartz. the li content of
hydrothermal quartz is greater near the centre of the white pine fork deposit than in its margins.
at buckingham, quartz in the breccia cement at the centre of the deposit shows the highest
concentration of al, li, k, ca, as, and sb, and metals (i.e. cu, fe, zn, and pb), whereas the
igneous and sedimentary quartz shows the highest ti values. the high values indicate that the
primary ti contents were not subjected to recalibration during hydrothermal alteration. the al
and sb contents of quartz decrease away from the centre of deposit at buckingham. this trend
was not observed at white pine fork.